Classification of Phosphating and Influence of Phosphating Wastewater on Environment

Release time:

2022-08-09 09:56

Pickling and phosphating wastewater is commonly found in electrophoresis, spraying, chemical industry, electroplating and other enterprises, and its pollutants are complex and changeable. Due to their different production processes, some also contain a certain amount of heavy metals such as nickel ions, copper ions or lead ions, as well as surfactants and other pollutants, which are extremely harmful. Moreover, phosphorus can cause eutrophication of water bodies, make the oxygen content of water bodies drop rapidly, and seriously endanger the ecological environment. (Generally speaking, when the total phosphorus content in the water reaches20mg/LIt is considered eutrophication).

16049727065148.jpg

Phosphating agents can be broadly divided into seven categories:

1) Normal temperature zinc phosphating agent: it can form gray, uniform and dense phosphating film on the surface of steel and zinc at normal temperature, which can be used as the bottom layer of paint to enhance the adhesion and rust resistance of paint.

2) Ternary phosphating solution: special phosphating solution for cathodic electrophoresis, suitable for surface treatment of steel before cathodic electrophoresis. Heating 40-45°C use, 3-5 minutes to form a dense phosphating film, phosphating film has a strong acid and alkali resistance, has a good penetration rate, can significantly improve the binding force of the substrate and the coating.

3) Iron-based phosphating agent: It is a light blue acidic liquid that can form a blue to iridescent phosphating film on the surface of steel. It has excellent compatibility with electrophoretic coatings and powder coatings, so that the paint film has excellent adhesion.

4) Zinc calcium phosphating solution: Use at a medium temperature of 60-70°C to form a dark gray phosphating film, the thickness of the phosphating film is 4-6um, and the neutral salt spray of the phosphating film can reach 48 hours.

(5) zinc manganese calcium phosphating solution: medium temperature 60-70°C use, the formation of gray black phosphating film, phosphating film thickness 4-6um, phosphating film neutral salt spray up to 48 hours.

(6) Wire drawing phosphating solution: suitable for surface treatment of steel wire before drawing. A dense gray phosphating film can be formed in a short time. The phosphating film has strong anti-rust ability and good wear resistance, and is suitable for deformation processing of steel products. The biggest advantage is the use of a single component phosphating solution, the operator without additives is also easy to control.

(7) pure manganese phosphating solution: high temperature 90-95°C use, the formation of pure black phosphating film, phosphating film thickness 8-10um, phosphating film neutral salt spray up to 96 hours.

 

Phosphating agent

Other News

The role of phosphating agent is obvious to all. It can not only bring rich benefits to modern machinery production, but also make new breakthroughs in improving the overall processing quality. With the continuous introduction of technology, the type of phosphating solution has also undergone many changes. Medium temperature phosphating solution, slag-free phosphating solution and galvanizing phosphating solution are all representatives of technological innovation. In order to give full play to its use value, manufacturers need to improve the operability of the spraying method, then, the following together to understand the main advantages of phosphating agent using spray method! On the one hand, manufacturers in the use of phosphating agent, comparative analysis of applicable methods. If the phosphating agent is sprayed directly on the surface of the workpiece, the formation speed of the phosphating film is much faster than that of the workpiece immersed in the same phosphating solution, or the phosphating can be carried out at the same time at a lower temperature. In the iron-containing phosphating solution, the iron ions will be oxidized by the atmosphere during the spraying phosphating process, so the spraying phosphating method cannot be used for iron salt phosphating. The spraying method is also not suitable for high-temperature manganese salt phosphating because the heat loss is too large. On the other hand, the spraying method is a method accepted by many manufacturers. The advantages are as follows: 1. The phosphating solution in contact with the metal surface is always fresh. Soaking methods are different. The phosphating solution in contact with the metal surface will gradually lack the film-forming ions, which can only be formed by the diffusion of the phosphating solution from a distance.


Phosphating agent technology has been developed for more than 100 years. For more than 100 years, phosphating technology has developed from a simple chemical corrosion method to a complex and comprehensive technology. The application scope of phosphating treatment technology has also developed from the initial metal anti-corrosion to today's metal coating pre-phosphating treatment, metal wear-resistant phosphating treatment, metal anti-corrosion phosphating treatment and metal plasticizing treatment. Phosphating treatment and other applications before denaturation processing, then, let's understand the development potential analysis of phosphating agent industry together! Statistics show that China's phosphate rock reserves account for 5.7 of the world's total, ranking second in the world, with an average grade of about 17%, of which intermediate phosphate rock (grade above 30%) accounts for only 16.7, while the price of phosphate rock in India is 210 US dollars/ton (68-70% BPL), equivalent to the domestic price of 1432 yuan/ton, which is about 1.5 times higher than the price in Hubei market. "China's phosphate rock 'many but not rich', high-grade phosphate rock is very scarce, the price difference at home and abroad is huge." Analysis of the development potential of the phosphating agent industry Phosphating agent refers to the chemical sub-industry that uses phosphate rock as raw material and processes the phosphorus element in the ore into products through chemical methods. The main products are yellow phosphorus, phosphate fertilizer, phosphoric acid, phosphate fertilizer, etc., which are widely used in daily chemicals, food, electronics, medicine, pesticides,


What are the problems of phosphating agent? The role of phosphating agent is mainly in two aspects: on the one hand, the phosphating agent plays the role of cathodic depolarization in the process of forming chemical conversion film, which promotes the normal progress of electrochemical conversion reaction, so as to ensure the normal progress of chemical deposition reaction, that is, the formation of chemical conversion layer. On the other hand, these accelerators are mostly oxidizing species. During the chemical conversion treatment, the ferrous ions dissolved in the iron-containing metal material treatment solution are oxidized to ferric ions, thereby preventing the enrichment of the ferric ions during the chemical conversion, preventing the aging of the chemical treatment solution due to the enrichment of the ferrous ions, and preventing the possibility of a good conversion layer. However, each of the regular chemical conversion phosphating agents has various problems to be solved. A wide range of sulfites are not stable in acid solutions and must be added continuously as an ingredient during use to replenish the amount of sulfite equivalent to consumption, thereby keeping the concentration of nitrous salt constant. More importantly, a part of the phosphite is converted into NOx gas during the oxidation or natural decomposition reaction, and the obtained NOx gas is diffused into the atmosphere and causes pollution. Chlorate alone is less effective when used as a chemical conversion phosphating agent. It is usually chemically transformed with another


What is the phosphating agent? Phosphating is a commonly used pretreatment technology. In principle, it belongs to chemical conversion surface treatment, which is mainly used in the phosphating of steel surface. Non-ferrous metals (such as aluminum and zinc) can also be used for phosphating. Phosphating is the process of chemical and electrochemical reaction of phosphate chemical conversion surface, called phosphating surface. The purpose of phosphating is mainly to provide protection for the base metal and prevent metal corrosion to a certain extent; it is used as a primer before painting to improve the adhesion and corrosion resistance of the paint surface; it plays a role in the cold working of the metal. Anti-friction and lubrication. The principle of the phosphating agent is that the chemical liquid itself reacts with the substrate, and a void-free chemical conversion surface layer appears on the surface of the substrate to protect the substrate. Phosphating agent is a kind of chemical widely used in the pretreatment of professional spraying plants. It can provide temporary rust prevention and good adhesive layer of paint and powder for spraying workpieces. Classification: Iron phosphating agent It is a light blue acidic coating that can appear on the surface of steel, zinc and aluminum with a thickness of 0.8-1.7 μm. It is the surface of yellow, red and blue. It has good compatibility with electrophoretic coating and powder coating, making the thin surface layer resistant to bending, deformation and strong resistance. The single-liquid product has stable performance, almost no precipitation, convenient tank management, and elimination.


Iron phosphating agent It is a light blue acidic coating that can form a thickness of 0.8-1.7 μm on the surface of steel, zinc and aluminum. It is a film of yellow, red and blue. It has good compatibility with electrophoretic coating and powder coating, making the film resistant to bending, deformation and strong resistance. The product is a single liquid, stable performance, almost no sediment, easy to tank liquid management, low cost, wide processing temperature. Zinc phosphating agent can form a gray, uniform and dense phosphate film on the surface of steel and zinc at room temperature. It can be used as a primer for paint and can enhance the adhesion and rust resistance of the paint. The product has a wide process range, and the film is formed quickly and uniformly. Each kilogram of concentrated solution can process the surface of the workpiece 30-40m. Low temperature phosphating solution is suitable for surface treatment of steel products. A dense phosphating film can be formed in a short time. The phosphating film has strong anti-rust ability and can significantly improve the adhesion between the substrate and the coating. The big advantage is that the plating solution is extremely stable, the phosphating time is short, the processing temperature is low, no heating equipment is required, the phosphating film is fine and uniform, the operating process is wide, and the deposit is small. It is an environmentally friendly phosphating solution. Galvanized plate phosphating solution is suitable for the phosphating treatment of galvanized plate products, as well as plating.